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eguruchela

Electrochemistry


Ohm's Law

v=IR R=ρla Where V is Potential difference, R is Resistance, I is current, ρ is specific resistance, l is lenght of conductor and  a is the cross-section of conductor.

Conductance

G=1R The specific conductance k =1ρ  Cell constant ρ=la k=G.σ

Molar conductance

Molar conductance AM(ΦC)=1000 x k C (or M) where C is concentration of electrolyte in terms of molarity.

Equivelant conductance

Equivelant conductance AM(AC)=1000 x k C (or N) where C is concentration(normality) AM=AN x(nfactor) Ao=limC0AC whereAo=equivalent conductance at infinite dilution.

Faraday's first law of electrolysis

m=Zit where m is mass of substance deposited,  Z is electrochemical equivalent, i is current and t is time. Z=Atomic massn x F Faraday's second law of electrolysis m1m1=E1E1 where E is equivalent weight.