Electrochemistry
Ohm's Law
v=IR
R=ρla
Where V is Potential difference,
R is Resistance,
I is current,
ρ is specific resistance,
l is lenght of conductor and
a is the cross-section of conductor.
Conductance
G=1R
The specific conductance k =1ρ
Cell constant ρ=la
k=G.σ
Molar conductance
Molar conductance AM(ΦC)=1000 x k C (or M)
where C is concentration of electrolyte in terms of molarity.
Equivelant conductance
Equivelant conductance AM(AC)=1000 x k C (or N)
where C is concentration(normality)
AM=AN x(n−factor)
Ao=lim
\text {where} A _{\,o} = \text {equivalent conductance at infinite dilution.}
Faraday's first law of electrolysis
m = Zit
\text {where m is mass of substance deposited, }
\text {Z is electrochemical equivalent,}
\text {i is current and}
\text {t is time.}
Z = \frac {\text{Atomic mass}}{\text{n x F}}
\text {Faraday's second law of electrolysis}
\frac {m _{\,1}} {m _{\,1}} = \frac {E _{\,1}} {E _{\,1}}
\text {where E is equivalent weight.}