Electrochemistry
Ohm's Law
v=IR
R=ρla
Where V is Potential difference,
R is Resistance,
I is current,
ρ is specific resistance,
l is lenght of conductor and
a is the cross-section of conductor.
Conductance
G=1R
The specific conductance k =1ρ
Cell constant ρ=la
k=G.σ
Molar conductance
Molar conductance AM(ΦC)=1000 x k C (or M)
where C is concentration of electrolyte in terms of molarity.
Equivelant conductance
Equivelant conductance AM(AC)=1000 x k C (or N)
where C is concentration(normality)
AM=AN x(n−factor)
Ao=limC→0AC
whereAo=equivalent conductance at infinite dilution.
Faraday's first law of electrolysis
m=Zit
where m is mass of substance deposited,
Z is electrochemical equivalent,
i is current and
t is time.
Z=Atomic massn x F
Faraday's second law of electrolysis
m1m1=E1E1
where E is equivalent weight.