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eguruchela

Electrochemistry


Ohm's Law

v=IR R=ρla Where V is Potential difference, R is Resistance, I is current, ρ is specific resistance, l is lenght of conductor and  a is the cross-section of conductor.

Conductance

G=1R The specific conductance k =1ρ  Cell constant ρ=la k=G.σ

Molar conductance

Molar conductance AM(ΦC)=1000 x k C (or M) where C is concentration of electrolyte in terms of molarity.

Equivelant conductance

Equivelant conductance AM(AC)=1000 x k C (or N) where C is concentration(normality) AM=AN x(nfactor) Ao=lim \text {where} A _{\,o} = \text {equivalent conductance at infinite dilution.}

Faraday's first law of electrolysis

m = Zit \text {where m is mass of substance deposited, } \text {Z is electrochemical equivalent,} \text {i is current and} \text {t is time.} Z = \frac {\text{Atomic mass}}{\text{n x F}} \text {Faraday's second law of electrolysis} \frac {m _{\,1}} {m _{\,1}} = \frac {E _{\,1}} {E _{\,1}} \text {where E is equivalent weight.}